| EPSRC Reference: |
EP/D054397/1 |
| Title: |
Bringing the 4th Dimension to Chemical Crystallography - Time Resolved Photocrystallography |
| Principal Investigator: |
Raithby, Professor PR |
| Other Investigators: |
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| Project Partners: |
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| Department: |
Chemistry |
| Organisation: |
University of Bath |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 April 2006 |
Ends: |
30 September 2010 |
Value (£): |
205,741
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| EPSRC Research Topic Classifications: |
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| EPSRC Industrial Sector Classifications: |
| Chemicals |
Pharmaceuticals and Biotechnology |
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Summary on Grant Application Form |
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The importance of knowing the structure of a material to atomic resolution, the number and nature of the connectivities between the atoms, is fundamental in understanding the properties of the material. X-ray crystallography is the best method of obtaining the detailed structure of solid materials, and provides a 3D picture of the structure. However, until now, it is a technique that only looks as molecules in their ground (unreactive) state. In this proposal, for the first time, we wish to introduce the dimension of time into the crystallographic experiment. By combining the X-ray experiment with a synchronised light source, that activates the molecules into an excited (reactive) state, we will look at the structures of species with lifetimes of microseconds or even nanoseconds. To achieve this we need to build protective molecular cages around these photoreactive molecules, and to compare their solid state behaviour with what occurs in solution using time resolved IR techniques.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.bath.ac.uk |