| EPSRC Reference: |
EP/H033343/1 |
| Title: |
Water transport in cements: A bottom - up approach based on NMR relaxation and imaging analysis and numerical modelling |
| Principal Investigator: |
McDonald, Professor P |
| Other Investigators: |
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| Researcher Co-Investigators: |
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| Project Partners: |
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| Department: |
Physics |
| Organisation: |
University of Surrey |
| Scheme: |
Standard Research |
| Starts: |
06 September 2010 |
Ends: |
05 December 2014 |
Value (£): |
762,055
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| EPSRC Research Topic Classifications: |
| Analytical Science |
Civil Engineering Materials |
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| EPSRC Industrial Sector Classifications: |
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| Related Grants: |
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| Panel History: |
| Panel Date | Panel Name | Outcome |
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10 Feb 2010
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Process Environment and Sustainability (PES)
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Announced
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Summary on Grant Application Form |
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Concrete is an inherently low energy input material (600-800 MJ/tonne) comparable to wood (500 MJ/tonne). However, the enormous quantities used worldwide mean that it accounts for at least 5% of global CO2 production with demand for cement set to double / treble by 2050 . Water movement in concrete is a key factor influencing the long term performance and degradation of infrastructure by both physical and chemical means. Moreover, water is a key constituent of cement, the primary binder phase of concrete. However, remarkably, there is as yet no clear understanding of pore-water interactions in cements. Equally there is no good predictor of water transport in concrete. To gain this understanding will achieve a critical step towards predicting the long-term performance of concrete and the design of new cement materials with lower cement CO2 emissions per unit of performance . To date, most approaches to the understanding of water transport in cement have been top down . Whether by experiment or modelling , cement is treated as a macroscopic material for which effective water diffusivities are either measured or calculated. It is largely an empirical science, with relatively little known to underpin the necessary assumptions about different water transport mechanisms. This programme proposes, for the first time, a concerted bottom up approach that begins with water transport in cement at the molecular (nm) level and builds to the macroscopic. At each stage, understanding gained at one length and time scale will underpin progress at the next. The goal is to develop and test a predictive model of water dynamics that can be incorporated within / bolted onto the current pre-eminent numerical model of cement chemistry and micro-structure, mu-IC, developed by Scrivener and co-workers at EPFL, Switzerland.The programme will be achieved by combining recent advances in nuclear magnetic resonance (NMR) relaxometry with equally impressive advances in numerical modelling of cement microstructure. NMR has opened an entirely new window to our understanding of pore water interactions and dynamics in cements at the nanoscale with identification of dynamics on timescales of 1 ns, 10 us and 5 ms. Advances in numerical modelling are based on advances in other spectroscopies and microscopies. Coupling the two creates new opportunity to understand, and hence create predictive capability for water transport in cements from the atomic scale upwards. This programme will be pursued in close collaboration with international collaborators leading in their fields: Professor Karen Scrivener, EPFL and Dr Sergey Churakov, PSI, Switzerland. Moreover, there is strong networking to a major intrnational cements research network of 15 industrial and 22 academic partners: NANOCEM. NANOCEM will contribute 57,000 including 35,000 cash to the programme and 22,000 for a 6 month PDRA at Surrey, up to March 2010. Project students and post-doctoral researchers will make extended visits to these collaborators.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.surrey.ac.uk |