| EPSRC Reference: |
EP/T016337/1 |
| Title: |
Intermediate range order effects in radioactive waste glasses: implications for aqueous durability and mechanical properties |
| Principal Investigator: |
Patel, Dr M K |
| Other Investigators: |
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| Researcher Co-Investigators: |
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| Project Partners: |
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| Department: |
Mech, Materials & Aerospace Engineering |
| Organisation: |
University of Liverpool |
| Scheme: |
Standard Research - NR1 |
| Starts: |
01 January 2021 |
Ends: |
31 December 2023 |
Value (£): |
863,375
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| EPSRC Research Topic Classifications: |
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| Related Grants: |
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| Panel History: |
| Panel Date | Panel Name | Outcome |
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22 Oct 2019
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UK-India Civil Nuclear Collaboration
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Announced
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Summary on Grant Application Form |
Radioactive waste occurs as a wide variety of radioactive elements that must be immobilised in a matrix of glass or ceramic or a composite, before disposal in a geological repository. This matrix, commonly known as the waste form, must be able to accommodate the wide range of species present in the waste and be resistant to leaching and mechanical fracture for the lifetime of radioactive species, typically 10,000 years or more. Glass, having an amorphous structure, is able to accommodate a wide range of radioactive waste species. In addition, glass fabrication technology is well established to produce these waste forms at large scale and this has been carried out for some years in both the UK and India, among several other countries.
The proposed project aims to understand the phase stability, thermal and radiation effects in radioactive waste glasses, in light of atomic scale structural changes due to radiation effects. These modifications will then be correlated with glass dissolution and mechanical properties such as cracking/fracture. The glasses selected are critical to the radioactive waste management programs in the UK and India, thus complementing methods and scientific expertise to realise clean, safe and economical energy from nuclear technology whilst presenting the most robust safety case for waste disposal. Our specific aims will be to: (1) understand the phase stability of glasses as a function of different divalent cations and addition of waste species; (2) define 'radiation damage' in an already amorphous/disordered material system and predict how radiation-induced modifications will affect dissolution properties over long timescales; and (3) understand the evolution of glass structure and properties under a temperature gradient and after undergoing annealing treatments.
In order that radioactive waste should no longer be deemed as an 'issue' rather than a practice that can be trusted by public opinion, the methods and materials employed to immobilise radioactive waste must be fundamentally understood and scientifically verified. This project aims at improving this confidence. Our detailed User Engagement Strategy will ensure that groups from the public and members of communities that may be involved in selection of a geological disposal facility, as well as the nuclear industry and supply chain, government and civil servants, and a wide range of academics, will be engaged throughout and beyond this project to deliver maximum impact from our proposed research.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.liv.ac.uk |