EPSRC Reference: |
EP/V048554/1 |
Title: |
Into a New Plane - Three-Dimensionally Delocalised Nano-Graphenes |
Principal Investigator: |
Wright, Dr I A |
Other Investigators: |
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Researcher Co-Investigators: |
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Project Partners: |
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Department: |
Chemistry |
Organisation: |
Loughborough University |
Scheme: |
Standard Research - NR1 |
Starts: |
01 April 2021 |
Ends: |
31 March 2022 |
Value (£): |
190,746
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EPSRC Research Topic Classifications: |
Materials Characterisation |
Materials Synthesis & Growth |
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EPSRC Industrial Sector Classifications: |
No relevance to Underpinning Sectors |
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Related Grants: |
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Panel History: |
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Summary on Grant Application Form |
Graphene is a cornerstone material in nanotechnology with its isolation in 2004 leading to the Nobel Prize in Physics for Geim and Novoselov in 2010. Graphene consists of a one-atom thick sheet of hexagonally arranged carbon atoms which share electrons to create a fully electronically delocalised surface. Nanographenes, and related graphene nanoribbons, are fragments of graphene which can be produced through controlled chemical synthesis. This has useful consequences such as reproducible synthesis and the ability to dictate the edge-structure structure of graphene. Controlling the edge-structure of these materials is key to their utility in applications including topological insulators, organic solar cells and hydrogen storage.
This project will establish a new dimension in graphene, literally. It will yield unique 3D nanographenes with controlled edge-structure which are synthesised using robust "bottom-up" synthetic pathways. This will allow for synthesis on a larger scale and improved solubility compared to existing planar nanographenes and graphene nanoribbons. Through pi-extension or self-assembly methods these new molecular materials will be transformed into hierarchical nanostructures to produce fully three-dimensionally delocalised supramolecular and macromolecular constructs. The optoelectronic properties of these new nanographenes, and assemblies thereof, will be quantified using advanced photophysical and electrochemical tools complemented by charge transport measurements and computational insights. Benchmarking these functional properties against existing 2D nanographenes, and graphene nanoplatelets themselves, will establish a new chemical space in nanotechnology and produce unprecedented novel molecular materials.
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Key Findings |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
Summary |
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Date Materialised |
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Sectors submitted by the Researcher |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Project URL: |
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Further Information: |
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Organisation Website: |
http://www.lboro.ac.uk |