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Details of Grant 

EPSRC Reference: GR/J42427/01
Title: FUNDAMENTAL STUDIES OF EXTRACTION AND SEPARATION OF METALS USING SUPERCRITICAL FLUIDS
Principal Investigator: Clifford, Professor AA
Other Investigators:
Bartle, Professor K
Researcher Co-Investigators:
Project Partners:
BNFL
Department: Sch of Chemistry
Organisation: University of Leeds
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 1993 Ends: 30 September 1996 Value (£): 207,438
EPSRC Research Topic Classifications:
Separation Processes
EPSRC Industrial Sector Classifications:
Environment
Related Grants:
Panel History:  
Summary on Grant Application Form
Supercritical fluid extraction (SFE) is becoming important on both an industrial and analytical scale. By controlling the solvent, temperature and pressure, SFE can, to some extent, be made selective. Equally important, especially as regulations become tougher, is that supercritical fluids such as carbon dioxide offer environmental advantages, by replacing more toxic organic solvents. Metal complexes have been shown recently to be soluble in modified carbon dioxide, by carrying out supercritical fluid chromatography and extraction. For reasons of both process improvement and the environment, investigation of the use of supercritical fluids for the extraction and separation of metals is desirable for the benefit of metal processing industries.We therefore intend, firstly to exhibit the feasibility, as an industrial process, of metal extraction and separation from both liquids and solids using supercritical fluids. Secondly, the conditions for optimisation of such a process of (a) the fluid used, (b) the temperature and pressure, (c) the complexing agent used, and (d) the experimental technique will be studied. Thirdly, we propose to investigate the selectivity of extraction obtained by different complexing agents and by varying other conditions.
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Organisation Website: http://www.leeds.ac.uk