EPSRC Reference: |
GR/J86445/01 |
Title: |
STUDIES OF MOLECULAR INTERACTIONS IN POLYMER BLENDS USING SYNCHROTRON-GENERATED TIME-RESOLVED LUMINESCENCE |
Principal Investigator: |
Soutar, Professor I |
Other Investigators: |
|
Researcher Co-Investigators: |
|
Project Partners: |
|
Department: |
Physics |
Organisation: |
Lancaster University |
Scheme: |
Standard Research (Pre-FEC) |
Starts: |
01 January 1995 |
Ends: |
30 June 1998 |
Value (£): |
116,335
|
EPSRC Research Topic Classifications: |
Materials Characterisation |
|
|
EPSRC Industrial Sector Classifications: |
|
Related Grants: |
|
Panel History: |
|
Summary on Grant Application Form |
The programme will examine the extent to which time-resolved luminescence measurements can be used to study molecular behaviour and interactions in polymer blends. The programme of work will contain the following elements:(i)Time-resolved energy transfer will be used, for the first time, in examination of molecular interpenetration in polymer blends. (Recent preliminary experiments have demonstrated the feasibility of such an approach - see Appendix to the Case for Support).(ii)Time-resolved anisotropy measurements will be used to study macromolecular dynamics in homogeneous, partially miscible and phase-separated blends. This approach, never previously applied to polymer blends, has been shown , in the applicant's laboratory, to yield information regarding polymer motions in both fluid and solid states. In particular, time-resolved phosphorescence measurements (recently performed for the first time in a synthetic polymer system, in the laboratory of the applicant) will be used to study macromolecular behaviour over the range of blend-types described in (i). (iii) Luminescence measurements will be used to study the aggregation (as predicted by theory) and mobilities of chain termini in the interphase regions of phase-separated polymers.
|
Key Findings |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
Potential use in non-academic contexts |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
Impacts |
Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
Summary |
|
Date Materialised |
|
|
Sectors submitted by the Researcher |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
Project URL: |
|
Further Information: |
|
Organisation Website: |
http://www.lancs.ac.uk |