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Details of Grant 

EPSRC Reference: GR/K18108/01
Title: COMPUTATIONAL MODELLING OF VINYL POLYMERS - WITH SPECIAL REFERENCE TO POLYVINYL ALCOHOL
Principal Investigator: Windle, Professor A
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Materials Science & Metallurgy
Organisation: University of Cambridge
Scheme: Standard Research (Pre-FEC)
Starts: 01 July 1994 Ends: 30 November 1997 Value (£): 123,927
EPSRC Research Topic Classifications:
Materials Characterisation
EPSRC Industrial Sector Classifications:
Related Grants:
Panel History:  
Summary on Grant Application Form
The proposed project lies in the general area of those vinyl polymers which have less than perfectly regular chains by virtue of ???: it is modelling-led and addresses the central issue of the crystallisation of aperiodic chains. There is a special focus on polyvinyl alcohol (PVOH), not only because of the long-standing question of the high crystallinity seen in samples which are both ??? and chain branched, but also because of the commercial possibilities afforded by the polymer when synthesised with stereospecific control. While the modelling work will embrace a range of vinyl polymers in order to achieve a general understanding of the relationship between chain irregularity and crystalline order, the attention given to PVOH will also involve some experimental work. It will include the synthesis of stereoregular samples using established laboratory routes, full molecular characterisation, and detailed diffraction analysis of the samples as a function of temperature and water content.
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Organisation Website: http://www.cam.ac.uk