EPSRC Reference: |
GR/K21788/01 |
Title: |
SYNTHESIS OF GROUP 8 ALKYLIDYNE COMPLEXES AS ROMP PRE-CATALYSTS |
Principal Investigator: |
Hill, Professor A |
Other Investigators: |
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Researcher Co-Investigators: |
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Project Partners: |
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Department: |
Chemistry |
Organisation: |
Imperial College London |
Scheme: |
Standard Research (Pre-FEC) |
Starts: |
15 October 1994 |
Ends: |
14 October 1997 |
Value (£): |
150,450
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EPSRC Research Topic Classifications: |
Chemical Synthetic Methodology |
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EPSRC Industrial Sector Classifications: |
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Related Grants: |
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Panel History: |
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Summary on Grant Application Form |
1. Develop synthetic routes to alkylidyne complexes of iron, ruthenium and osmium.2. Define reactivity profiles for alkylidyne ligands as a function of metal, co-ligands and co-ordinative unsaturation of comparison with early transition metal alkylidyne complexes.3. Investigate the coupling reactions of alkylidyne ligands with other unsaturated co-ligands, directed towardsa) Elaboration of novel ligands andb) Application to metal mediated organic synthesis.4. investigate the suitability of the alkylidyne complexes as pre-catalysts for olefin metathesis processes.
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Key Findings |
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Potential use in non-academic contexts |
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Impacts |
Description |
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Summary |
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Date Materialised |
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Sectors submitted by the Researcher |
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Project URL: |
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Further Information: |
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Organisation Website: |
http://www.imperial.ac.uk |