| EPSRC Reference: |
GR/K78904/01 |
| Title: |
A NOVEL APPROACH TO BIPYRIDINES BY DOUBLE INTRAMOLECULAR DIELS-ALDER REACTIONS. |
| Principal Investigator: |
Moody, Professor CJ |
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| Department: |
Chemistry |
| Organisation: |
University of Exeter |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 October 1996 |
Ends: |
30 September 1999 |
Value (£): |
6,396
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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Summary on Grant Application Form |
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It is proposed to develop a novel double intermolecular Diels-Alder reaction of azadienes with alkynes as a route to bipyridines. The scope of the reaction as a route to annelated bipyridienes will be investigated, and it will be extended to the synthesis of a range of chiral bipyridienes as potential ligands for asymmetric synthesis. The double intramolecular Diels-Alder reaction will also be used in the synthesis of the polycyclic marine natural product eilatin. Finally the use for the novel chiral bipyridienes in asymmetric hydrosilylation, cyclopropanation and diethylzinc addition reactions will be studied.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.ex.ac.uk |