EPSRC Reference: |
GR/K85162/02 |
Title: |
DESIGN OF ULTRA SELECTIVE CATALYSTS FOR ETHANE OXIDATION |
Principal Investigator: |
Hutchings, Professor G |
Other Investigators: |
|
Researcher Co-Investigators: |
|
Project Partners: |
|
Department: |
Chemistry |
Organisation: |
Cardiff University |
Scheme: |
Standard Research (Pre-FEC) |
Starts: |
01 October 1997 |
Ends: |
31 March 2000 |
Value (£): |
97,704
|
EPSRC Research Topic Classifications: |
Catalysis & Applied Catalysis |
|
|
EPSRC Industrial Sector Classifications: |
|
Related Grants: |
|
Panel History: |
|
Summary on Grant Application Form |
The major objective of this work is to investigate the important features involved in the selective activation of ethane on oxide surfaces. This information will then be used to design novel high activity ultra selective catalysts for the single stage conversion of ethane to acetic acid. The identification of such a one step process will be more energy and carbon efficient when compared with the existing technology based on methanol carbonylation and will represent a major advance in clean technology. Initial catalysts will be based on V containing catalysts incorporating the V(IV)/V(V) oxidation couple. Experiments designed to probe oxygen activation (18O/16O exchange) and hydrocarbon activation (D/H exchange) will be used initially and it is anticipated that the research will be of generic value for hydrocarbon activation in general.
|
Key Findings |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
Potential use in non-academic contexts |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
Impacts |
Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
Summary |
|
Date Materialised |
|
|
Sectors submitted by the Researcher |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
|
Project URL: |
|
Further Information: |
|
Organisation Website: |
http://www.cf.ac.uk |