| EPSRC Reference: |
GR/K88781/01 |
| Title: |
CROWNED PORPHYRAZINES IN ENANTISELECTIVE SYNTHESIS |
| Principal Investigator: |
Barrett, Professor T |
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| Department: |
Chemistry |
| Organisation: |
Imperial College London |
| Scheme: |
ROPA |
| Starts: |
01 January 1997 |
Ends: |
30 June 1999 |
Value (£): |
103,162
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Summary on Grant Application Form |
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The objectives of this research are the design and synthesis of chiral porphyrazinoctaol derivatives with C4 symmetry and the application of the derived chloroiron(III), chloromanganese (III) and (pyridene)(carbonyl)osmium(II) complexes in both asymmetric epoxidation and cyclopropanation reactions. These catalysts should be readily available via short synthetic sequences and in homochiral form as either enantiomer starting from inexpensive (D)- or (L)-diethyl tartrate. Efficient and inexpensive methods for enantioselective synthesis are of vital importance for the industrial manufacture of diverse pharmaceuticals, agrochemicals and other speciality chemicals.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.imperial.ac.uk |