EPSRC Reference: |
GR/L32989/01 |
Title: |
DIFFUSION OF SORBATES IN MICROPOROUS SOLIDS BY FREQUENCY-RESPONSE METHODS |
Principal Investigator: |
Rees, Professor LV |
Other Investigators: |
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Researcher Co-Investigators: |
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Project Partners: |
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Department: |
Sch of Chemistry |
Organisation: |
University of Edinburgh |
Scheme: |
Standard Research (Pre-FEC) |
Starts: |
01 July 1997 |
Ends: |
31 March 2001 |
Value (£): |
149,762
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EPSRC Research Topic Classifications: |
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EPSRC Industrial Sector Classifications: |
No relevance to Underpinning Sectors |
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Related Grants: |
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Panel History: |
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Summary on Grant Application Form |
A through study of single file diffusion in zeolites will be carried out. Comparison with corresponding 3D networks and networks with dead-end pores and interconnecting channels of dimensions different from those of the main channels will be determined. Catalystic studies with these zeolites will be carried out and product distributions determined. The effect of surface resistance and coking will be studied. P-xylene diffusion in the hysteresis loop region of p-xylene/silicalite-1 will be measured. Acid and redox sites will be characterised using the FR method and various probe molecules at catalytic temperatures. Molecular dynamic simulations will be used to obtain a better understanding of the processes involved.
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Key Findings |
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Potential use in non-academic contexts |
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Impacts |
Description |
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Summary |
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Date Materialised |
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Sectors submitted by the Researcher |
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Project URL: |
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Further Information: |
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Organisation Website: |
http://www.ed.ac.uk |