EPSRC Reference: |
GR/L73579/01 |
Title: |
ROPA: OXYGEN ISOTOPIC EXCHANGE IN NOVEL OXYGEN EXCESS MIXED CONDUCTING OXIDES |
Principal Investigator: |
Kilner, Professor JA |
Other Investigators: |
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Researcher Co-Investigators: |
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Project Partners: |
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Department: |
Materials |
Organisation: |
Imperial College London |
Scheme: |
ROPA |
Starts: |
16 February 1998 |
Ends: |
15 February 2000 |
Value (£): |
119,597
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EPSRC Research Topic Classifications: |
Materials Characterisation |
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EPSRC Industrial Sector Classifications: |
No relevance to Underpinning Sectors |
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Related Grants: |
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Panel History: |
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Summary on Grant Application Form |
The aim of this work is to develop an atomistic model for the surface exchange of oxygen between a ceramic oxide and the ambient gas. The kinetics of oxygen exchange will be measured for mixed conducting oxides, with the K2NiF4 and related structures, as a function of temperature, partial pressure of oxygen, doping levels and surface orientation. These oxides have been chosen as they change stoichiometry from oxygen excess (interstitials) to oxygen deficiency (vacancies). Data on surface orientation effects will be obtained from single crystals, and by the use of a combination of EBSP and SIMS on ceramic samples.
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Key Findings |
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Potential use in non-academic contexts |
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Impacts |
Description |
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Summary |
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Date Materialised |
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Sectors submitted by the Researcher |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Project URL: |
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Further Information: |
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Organisation Website: |
http://www.imperial.ac.uk |