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Details of Grant 

EPSRC Reference: GR/L73869/01
Title: ROPA:TOWARDS A GENERIC METHOD FOR SELF-ASSEMBLING COMPLEX, POLYFUNCTIONAL MOLECULES ON ULTRA-CLEAN SURFACES
Principal Investigator: Raval, Professor R
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Chemistry
Organisation: University of Liverpool
Scheme: ROPA
Starts: 01 April 1998 Ends: 31 March 2000 Value (£): 99,827
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology
EPSRC Industrial Sector Classifications:
Chemicals
Related Grants:
Panel History:  
Summary on Grant Application Form
Self assembled monolayers (SAMs) are promising materials for molecular recognition, sensors, display devices, etc. However, their applications are limited due to the sparcity of systems capable of forming well-organised self assembled monolayers. We suggest a radical change of approach which will lead to the production of a completely new range of SAMs. We have recently discovered that ultra-clean surfaces provide good substrates onto which complex molecules can be assembled to give stable, crystalline-like monolayers. In order to develop more complex SAMs from a new range of polyfunctional molecules we propose a novel method of depositing these involatile substances onto ultra clean surfaces using a combination of electrospray techniques, mass filter extraction and 'soft-landing' optics. If successful, this will provide a generic route towards more sophisticated SAMs, capable of advanced chemical and optical functions.
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Organisation Website: http://www.liv.ac.uk