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Details of Grant 

EPSRC Reference: GR/M69982/01
Title: STUDY OF NANOCRYSTAL-POLYMER COMPOSITES FOR BLUE LIGHT EMITTING DIODES
Principal Investigator: Kelly, Professor S
Other Investigators:
O'Neill, Professor M Hogg, Dr J Scott, Dr C
O'Neil, Dr M Stirner, Dr T Nicholls, Dr J
Researcher Co-Investigators:
Project Partners:
DERA
Department: Physics
Organisation: University of Hull
Scheme: Standard Research (Pre-FEC)
Starts: 01 October 1999 Ends: 30 September 2002 Value (£): 173,020
EPSRC Research Topic Classifications:
Materials Synthesis & Growth
EPSRC Industrial Sector Classifications:
Aerospace, Defence and Marine Chemicals
Electronics
Related Grants:
Panel History:  
Summary on Grant Application Form
Novel nanocrystals of ZnTe coated with a MgTe shell will be incorporated into conducting polymer structures for high brightness blue light emitting diodes (LEDs). Such nanocrystals will have a bandgap that can be tuned between 400 and 500 nm by choice of nanocrystal size and shell thickness. The distinctive feature of the tellurides is their low work function when compared with the other wide bandgap II-VI compounds of sulphur and sellenium. Importantly the low work function minimises the hole transport barrier from the hole conducting polymer layer into the nanocrystals and should give the most efficient hole injection into any of the wide bandgap nanocrystals. The LEDs will be formed by spin coating a hole conducting polymer layer onto indium-tin-oxide (ITO) coated glass before spin coating the nanocrystals from suspension and contacting with a low work function metal such as calcium. Initially proprietary polymers and polymers from DERA will be used, but later in-house polymers with improved mobilities will become available as part of two current EPSRC contracts, leading to improved brightness of the LEDs. There are no previous reports of ZnTe or ZnTe/MgTe nanocrystals for optoelectronics.
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Further Information:  
Organisation Website: http://www.hull.ac.uk