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Details of Grant 

EPSRC Reference: GR/M74030/01
Title: HETERODITOPIC RECEPTORS FOR ANION AND CATION BINDING
Principal Investigator: Beer, Professor PD
Other Investigators:
Researcher Co-Investigators:
Project Partners:
Department: Oxford Chemistry
Organisation: University of Oxford
Scheme: Standard Research (Pre-FEC)
Starts: 01 May 2000 Ends: 30 April 2003 Value (£): 66,518
EPSRC Research Topic Classifications:
Co-ordination Chemistry
EPSRC Industrial Sector Classifications:
Environment Water
No relevance to Underpinning Sectors
Related Grants:
Panel History:  
Summary on Grant Application Form
The project is concerned with a new area of co-ordination chemistry, the design and syntheses of heteroditopic receptors for the simultaneous complexation of anionic and cationic guest species, ion-pair recognition. The receptor host framework contains binding sites for anionic and cationic guests covalently linked together and fashioned to be selective for target ion-pair group 1 metal salts and zwitterionic guests. Using a variety of spectroscopic and electrochemical techniques extensive co-ordination studies will be elucidate selectivity trends and the mutual anion-cation co-operative, synergistic and allosteric properties these ditopic systems display. Neutral ditopic receptors will be prepared specifically for solubilisation, extraction and selective carrier-assisted transportation of metal salts across lipophilic liquid membranes.
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Further Information:  
Organisation Website: http://www.ox.ac.uk