| EPSRC Reference: |
GR/T27228/01 |
| Title: |
Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry |
| Principal Investigator: |
Mulvey, Professor R |
| Other Investigators: |
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| Researcher Co-Investigators: |
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| Project Partners: |
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| Department: |
Pure and Applied Chemistry |
| Organisation: |
University of Strathclyde |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 May 2005 |
Ends: |
31 January 2009 |
Value (£): |
261,670
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| EPSRC Research Topic Classifications: |
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| EPSRC Industrial Sector Classifications: |
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| Related Grants: |
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| Panel History: |
| Panel Date | Panel Name | Outcome |
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01 Sep 2004
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Chemistry Prioritisation Panel (Science)
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Deferred
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Summary on Grant Application Form |
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The basic premise of the project is that when two distinct metal atoms are combined within the same molecular environment, a special new chemistry can emerge which cannot be replicated by either of the single metal components on their own. Established through alkali metal-magnesium precedents, this duplex synergy can be manifested in inverse crown ring systems, an acclaimed and exciting new field of research in which polymetallic cationic host rings encapsulate anionic guests, through unique reactions such as regioselective multimetallation.This project argues that based on literature precedents, it can deliver synergic (amide or O-ligand) systems in which magnesium (II) is replaced by other important binary metals including Ca, Zn, Cr(II), Mn(II) and Fe(II). Thus, the first transition metal inverse crowns will be synthesised, opening the way to a rich and diverse chemistry (involving, for example, redox processes; magnetic macrocycles; electrochemistry; metal-metal communication) impossible for the oxidation state fixed all s-block inverse crowns. Using tried and tested methodology, the synergic abilities of the new mixed-metal partnerships will be evaluated by subjecting them to a pool of pro-guest substrates. A plethora of ring-sizes and -shapes is envisioned for the new complexes, providing unique insight into the ways in which polymetallic cationic rings can direct and control anion complexation.
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Key Findings |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk |
| Summary |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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| Project URL: |
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| Further Information: |
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| Organisation Website: |
http://www.strath.ac.uk |