| EPSRC Reference: |
GR/J64900/01 |
| Title: |
SYNTHETIC AND MECHANISTIC STUDIES OF NOVEL RADICAL ADDITION REACTIONS |
| Principal Investigator: |
Roberts, Professor B |
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| Department: |
Chemistry |
| Organisation: |
UCL |
| Scheme: |
Standard Research (Pre-FEC) |
| Starts: |
01 December 1994 |
Ends: |
30 November 1996 |
Value (£): |
96,855
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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Summary on Grant Application Form |
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To develop radical chain reactions, of importance in organic synthesis, based on novel homolytic addiction reactions of unsaturated molecules. The emphasis will be on C-C bond formulation. Addition to, inter alia, isocyanides, alkylidene ylids, diazoalkanes, vinylic azides, imines and iminium ions will be investigated. Polar effect will be exploited to direct and control homolytic addition.2 To use ESR spectroscopy to study the elementary radical reactions involved in these chain processes and to apply the mechanistic knowledge gained to guide the progression of the preparative work.
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Key Findings |
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Potential use in non-academic contexts |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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Impacts |
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| Description |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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