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Details of Grant 

EPSRC Reference: GR/J84182/01
Title: NUCLEATION MECHANISMS AND THEIR EXPLOITATION FOR THE SELECTIVE AREA GROWTH OF CVD DIAMOND
Principal Investigator: Jackman, Professor RB
Other Investigators:
Foord, Professor J
Researcher Co-Investigators:
Project Partners:
Department: Electronic and Electrical Engineering
Organisation: UCL
Scheme: Standard Research (Pre-FEC)
Starts: 15 April 1994 Ends: 14 October 1997 Value (£): 169,504
EPSRC Research Topic Classifications:
Materials Synthesis & Growth
EPSRC Industrial Sector Classifications:
Electronics
Related Grants:
Panel History:  
Summary on Grant Application Form
It is believed that a potential multi-billion dollar worldwide annual market exists for high quality thin films of diamond. At present, microwave plasma enhanced chemical vapour deposition (MWPECVD) represents an effective method for the growth of diamond on non-diamond substrates at low pressures and at reasonable cost. However, films produced are typically polycrystaline and highly defective in nature severely hindering the prospects for commercial exploitation of the films. A recent breakthrough in the field has shown that a biased-MWPECVD nucleation step prior to thin film growth enables epitaxially orientated diamond to be grown on Si(100). Nothing is known concerning the mechanism by which this nucleation enhancement is achieved. This project aims to uncover the mechanism and to use this information to consider the prospects for the promotion of spatially controlled nucleation by non MWPECVD methods to enable high quality selective area CVD growth to be carried out.
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