| EPSRC Reference: |
GR/K90425/01 |
| Title: |
(ROPA) SYNTHESIS OF IMIDOMETALLASILOXANES & CATIONIC IMIDO-METAL COMPLEXES AS NEW CLASSES OF OLEFIN |
| Principal Investigator: |
Sullivan, Professor A |
| Other Investigators: |
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| Department: |
Chemistry |
| Organisation: |
Queen Mary University of London |
| Scheme: |
ROPA |
| Starts: |
01 October 1996 |
Ends: |
30 September 1999 |
Value (£): |
72,774
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| EPSRC Research Topic Classifications: |
| Chemical Synthetic Methodology |
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Summary on Grant Application Form |
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The Kaminsky and Schrock catalyst systems Cp2ZrX2/MAO and [{(CF3)2MeCO}2MoCHBu+(NR)] have attracted enormous industrial interest and broad patent cover is in place. The current proposal outlines feasible methods for the synthesis of high oxidation state imidometallasiloxanes and cationic imidometal complexes. On the basis of rational comparisons between imido and cyclopentadienyl ligands and alkoxy and siloxy ligands a new generation of Kaminsky and Schrock type catalysts may be expected from this work.
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Key Findings |
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Potential use in non-academic contexts |
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Impacts |
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| Description |
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| Date Materialised |
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Sectors submitted by the Researcher |
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This information can now be found on Gateway to Research (GtR) http://gtr.rcuk.ac.uk
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