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Details of Grant 

EPSRC Reference: GR/M27654/01
Title: ELEMENTAL FLUORINE AS A VIABLE REAGENT
Principal Investigator: Chambers, Professor R
Other Investigators:
Researcher Co-Investigators:
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Department: Chemistry
Organisation: Durham, University of
Scheme: ROPA
Starts: 01 November 1998 Ends: 31 October 1999 Value (£): 52,808
EPSRC Research Topic Classifications:
Chemical Synthetic Methodology
EPSRC Industrial Sector Classifications:
No relevance to Underpinning Sectors
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Summary on Grant Application Form
Elemental fluorine is already manufactured on a large scale and, in future it is probable that it will be recovered from 'spent' uranium hexafluoride by industry. We will explore methodology for fluorinating carbanions, especially using flow reactors developed in Durham, and we anticipate that this methodology will be applicable to chiral delivery of fluorine, either from chiral carbanions or via novel and recoverable chiral fluorinating agents. Synthesis of N-F compounds that are soluble in flurous-biphase systems will lead to processes that are selective and applicable for recycling.
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